Hi SSN...good observation.
Indeed higher octane fuel may react this way depending on your prop loading. (pitch) Just unload it a bit and all should be fine.
What is happening is the 100LL in effect burns slower than the auto fuel. The lower octane is easier to ignite but this also can have a greater tendency toward detonation. Higher octane fuel is very good at preventing detonation and is much safer for the engine. So the answer to your problem is yes, it indeed is burning slower and is better protection for the engine. Just reset the prop to get back to your normal RPM numbers and the performance will feel exactly the same.
If in your region it gets cold at all, winter flying, the 100LL will also be harder to start. Should that be the case you will need to do some pre-heat of the engine to solve that. (keep it in a hanger for example if possible)
Cheers